In the 1800s, foam was first used as an extinguishing agent with a mixture of aluminum sulfate and which other compound?

Foam was first used as an extinguishing agent in the 1800s through a mixture of aluminum sulfate and sodium bicarbonate. The reaction between these two compounds produces carbon dioxide gas, which creates the foam that smothers flames, thereby helping to suppress the fire. This foam is effective in covering flammable liquids and solids, reducing the oxygen supply to the fire while also cooling it.

Sodium bicarbonate is particularly valuable in extinguishing fires because when it heats up, it breaks down to produce carbon dioxide gas, which adds to the foam generation. This attribute allowed early fire-fighting efforts to become more effective and efficient by providing a means of controlling and extinguishing fires safely.

The other compounds listed do not create the same beneficial reaction in combination with aluminum sulfate for fire suppression purposes.