Which type of foam is most versatile for use on hydrocarbon fuels and polar solvents?

Alcohol-resistant aqueous film-forming foam (AR-AFFF) is the most versatile type of foam for use on both hydrocarbon fuels, such as gasoline and oil, and polar solvents, like alcohols. This is largely due to its formulation, which includes the ability to resist the solvent effects of alcohols that could break down other foam types.

When applied to hydrocarbon fires, AR-AFFF creates a film that spreads across the surface of the fuel, preventing re-ignition and smothering the flames. This film also has an affinity for aqueous materials, allowing it to be effective on polar solvents that can mix with water. This capability makes AR-AFFF a dual-purpose solution, suitable for a wider range of fire scenarios compared to other foam types.

Other foams, such as protein foam, are traditionally used for hydrocarbon fires but lack efficacy against polar solvents. Similarly, dry chemical foams do not form a film and are not designed to handle liquid fuels effectively, particularly those that are polar. The versatility of AR-AFFF in addressing both fire types ensures it remains the preferred choice in firefighting operations involving mixed fuel scenarios.